Multielectron transfer in a dicopper(II) anthraquinophane.
نویسندگان
چکیده
The new dinuclear copper(II) metallacyclophane with the non-innocent N,N'-1,4-bis(oxamate)-9,10-anthraquinone bridging ligand possesses a dual multielectron redox behavior featuring stepwise one-electron oxidation of the antiferromagnetically coupled Cu(II) ions and two-electron reduction of the anthraquinone spacers in a π-stacked anti conformation.
منابع مشابه
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ورودعنوان ژورنال:
- Chemical communications
دوره 49 34 شماره
صفحات -
تاریخ انتشار 2013